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当前位置: 首页 > 产品中心 > peptide > alfa/12764Bis(dibenzylideneacetone)palladium(0)/0.25g/12764.01
商品详细alfa/12764Bis(dibenzylideneacetone)palladium(0)/0.25g/12764.01
alfa/12764Bis(dibenzylideneacetone)palladium(0)/0.25g/12764.01
alfa/12764Bis(dibenzylideneacetone)palladium(0)/0.25g/12764.01
商品编号: 12764.01
品牌: 阿法埃莎
市场价: ¥11620.00
美元价: 5810.00
产地: 美国(厂家直采)
公司:
产品分类: 多肽合成
公司分类: peptide
联系Q Q: 3392242852
电话号码: 4000-520-616
电子邮箱: info@ebiomall.com
商品介绍

Bis(dibenzylideneacetone)palladium(0)

MDL
MFCD00051942

化学性质

化学式
C34H28O2Pd
式量
575.00
表格
Powder, Packaged under argon
熔点
135° dec.
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Store under Argon.Ambient temperatures.
可溶性
Slightly soluble in CH{2}Cl{2}, CHCl{3} and benzene.Soluble in dichloromethane, chloroform, 1,2-dichloroethane, acetone, acetonitrile and benzene. Insoluble in water.

应用

Hydrogenation, isomerization, carbonylation, oxidation, C-C bond formation.Bis(dibenzylideneacetone)palladium(0) is used as a reagent for the preparation of allylic substituted cyclopentadienes. It acts as a homogeneous catalyst as well as in the alkylation of allyl acetates by various nucleophiles. Further, it is used in Suzuki reaction.

注释

Incompatible with strong oxidizing agents.

参考文献

Chan, K. S.; Fu, H. Y.; Yu, J. Q. Palladium(II)-Catalyzed Highly Enantioselective C-H Arylation of Cyclopropylmethylamines. J. Am. Chem. Soc. 2015, 137 (5), 2042-2046.

Son, S.; Lee, H.; Kwak, C.; Lee, J.; Ahn, H.; Chung, M. A Study of Phosphorescent Light Emitting Using Cyclometalated Pt(II) Complexes. J. Nanosci. Nanotechnol. 2015, 15 (7), 5338-5341.

GHS危险和防护声明

危险说明(欧盟):H317

May cause an allergic skin reaction.

防范说明:P261-P272-P280g-P302+P352-P333+P313-P363-P403-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Store in a well-ventilated place. Dispose of contents/ container to an approved waste disposal plant

其他参考资料

协调关税代码
2843.90
有毒物质控制法
No

文件

产品 SDS

质量分析报告(COA)

产品说明书

品牌介绍
Alfa拥有广泛的产品线,包括无机、有机和金属有机化合物;纯金属和元素;贵金属化合物和催化剂;燃料电池产品;生化;纳米材料;稀土;分析类产品和一流的实验室器材。依托其母公司强大的全球生产网络及其它合作伙伴,我们能为客户提供最高品质的系列产品。Alfa Aesar的产品和服务已遍布医药行业、电子行业、学术机构及其他研发领域。