Bis(dibenzylideneacetone)palladium(0)
化学性质
应用
Hydrogenation, isomerization, carbonylation, oxidation, C-C bond formation.Bis(dibenzylideneacetone)palladium(0) is used as a reagent for the preparation of allylic substituted cyclopentadienes. It acts as a homogeneous catalyst as well as in the alkylation of allyl acetates by various nucleophiles. Further, it is used in Suzuki reaction.
注释
参考文献
Chan, K. S.; Fu, H. Y.; Yu, J. Q. Palladium(II)-Catalyzed Highly Enantioselective C-H Arylation of Cyclopropylmethylamines. J. Am. Chem. Soc. 2015, 137 (5), 2042-2046.
Son, S.; Lee, H.; Kwak, C.; Lee, J.; Ahn, H.; Chung, M. A Study of Phosphorescent Light Emitting Using Cyclometalated Pt(II) Complexes. J. Nanosci. Nanotechnol. 2015, 15 (7), 5338-5341.
GHS危险和防护声明
危险说明(欧盟):H317
May cause an allergic skin reaction.
防范说明:P261-P272-P280g-P302+P352-P333+P313-P363-P403-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Store in a well-ventilated place. Dispose of contents/ container to an approved waste disposal plant
其他参考资料
文件
产品 SDS
质量分析报告(COA)
产品说明书