Bis(tri-o-tolylphosphine)palladium(0), Pd 14.9%
化学性质
应用
Bis(tri-o-tolylphosphine)palladium(0) is used as a catalyst for palladium-catalyzed cross-coupling reactions, Kumada coupling and Heck coupling. It is also used in the amination and arylation reactions.
注释
参考文献
Hering, F.; Radius, U. From NHC to Imidazolyl Ligand: Synthesis of Platinum and Palladium Complexes d10-[M (NHC)2](M= Pd, Pt) of the NHC 1, 3-Diisopropylimidazolin-2-ylidene. Organometallics 2015, 34 (13), 3236-3245.
Stambuli, J. P.; Bühl, M.; Hartwig, J. F. Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand. J. Am. Chem. Soc. 2002, 124 (32), 9346-9347.
GHS危险和防护声明
危险说明（欧盟）:H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
防范说明:P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Take off contaminated clothing and wash before reuse. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/ container to an approved waste disposal plant
其他参考资料
文件
产品 SDS
质量分析报告(COA)
产品说明书
