Palladium(II) 2,4-pentanedionate, Pd 34.7%
化学性质
应用
It is used in carbonylation, oligomerization, and as a catalyst precursor for various synthetic organic transformations, for example in the preparation of complexes to efficiently catalyze Heck reaction.Useful in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides, in the preparation of monodisperse nanoparticles of CuPd alloy and in several cross-coupling reactions.
注释
参考文献
Wang, Y.; Hu, J.; Cai, Y.; Xu, S.; Weng, B.; Peng, K.; Wei, X.; Wei, T.; Zhou, H.; Li, X.; Liang, G. An Oxygen-Chelate Complex, Palladium Bis-acetylacetonate, Induces Apoptosis in H460 Cells via Endoplasmic Reticulum Stress Pathway Rather than Interacting with DNA. J. Med. Chem. 2013, 56 (23), 9601-9611.
Huang, L.; Wang, Y.; Wang, Z.; Chen, F.; Tan, J.; Wong, P. K.Heck Chemistry - a Highly Active Ligand-Free Metal Catalyst System in Situ Generated from PdII Supported on SiO2.Phys. Chem. 2012, 2 (1), 27-34.
Hamid, M.; Zeller, M.; Hunter, A. D.; Mazhar, M.; Tahir, A. A.; Redetermination of bis¬(2,4-pentane¬dionato)¬palladium(II). Acta Crystallogr. E 2005, 61 (11), 2181-2183.
GHS危险和防护声明
危险说明（欧盟）:H317-H318
May cause an allergic skin reaction. Causes serious eye damage.
防范说明:P261-P272-P280-P302+P352-P305+P351+P338-P310-P363-P403-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store in a well-ventilated place. Dispose of contents/ container to an approved waste disposal plant
其他参考资料
文件
产品 SDS
质量分析报告(COA)
产品说明书
