Palladium(II) acetate, Pd 45.9-48.4%
化学性质
应用
Palladium(II)acetate is a catalyst of choice for a wide variety of reactions such as vinylation, Wacker process, Buchwald-Hartwig amination, carbonylation, oxidation, rearrangement of dienes (e.g., Cope rearrangement), C-C bond formation, reductive amination, etc.Precursor to Pd(0), other Pd(II) compounds of catalytic significance, and Pd nanowires.
注释
参考文献
Zhang, S.; Shi, L.; Ding, Y. Theoretical Analysis of the Mechanism of Palladium(II) Acetate-Catalyzed Oxidative Heck Coupling of Electron-Deficient Arenes with Alkenes: Effects of the Pyridine-Type Ancillary Ligand and Origins of the meta-Regioselectivity. J. Am. Chem. Soc. 2011, 133 (50), 20218-20229.
Albert, J.; Granell, J.; Tavera, R. On the Mechanism of the Cyclopalladation Reaction of Benzyl-benzylidene-Amine with Palladium(II)acetate in Acetic acid. J. Organomet. Chem. 2003, 667, 192-196.
GHS危险和防护声明
危险说明(欧盟):H318
Causes serious eye damage.
防范说明:P280-P305+P351+P338-P310-P390-P406b-P501c
Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Absorb spillage to prevent material damage. Store in corrosive resistant polypropylene container with a resistant inliner Dispose of contents/ container to an approved waste disposal plant
其他参考资料
文件
产品 SDS
质量分析报告(COA)
产品说明书