Palladium(II) chloride, 99.9% (metals basis), Pd 59.0% min
化学性质
应用
Catalyst precursor.Palladium(II) chloride is used to remove the stain present in stainless steel . Its solutions are used to test the corrosion-resistance of stainless steel. It is used in carbon monoxide detectors. It is also used for cosmetic tattooing of leukomas in the cornea and in the preparation of palladium(II) iodide by reacting with potassium iodide. It is involved in the synthesis of semiconducting metal-containing polymers. It is used as a catalyst for carbonylation of organic tellurides and deamination of phenethylamines to phenyl substituted pyrroles with copper(I) as co catalyst. It plays an important role in the hydrodimerization of butadiene to form octa-2,7-dien-1-ol.
注释
参考文献
Yamaguchi, T.; Yamaguchi, E.; Tada, N.; Itoh, A. Direct ortho-Hydroxylation of 2-Phenylpyridines using Palladium(II) Chloride and Hydrogen Peroxide. Adv. Synth. Catal. 2015, 357 (9), 2017-2021.
Banti, C. N.; Charalampou, D. C.; Kourkoumelis, N.; Owczarzak, A. M.; Kubicki, M.; Hadjikakou, S. K.; Hadjiliadis, N. Mono-nuclear cis-Pd(II) chloride complex of the thio-nucleotide analogue 5-methyl-thiouracil and its biological activity. Polyhedron 2015, 87, 251-258.
Janreddy, D.; Kavala, V.; Kotipalli, T.; Kuo, C.; Kuo, T.; Chen, M.; He, T.; Yao, C. Palladium(II) Chloride-Catalyzed Aerobic Oxidative Intermolecular Cycloaddition Reaction of 2-Alkynylbenz- aldehydes and Electron-Deficient Terminal Alkenes: An Efficient Synthesis of Naphthyl Ketones. Adv. Synth. Catal. 2014, 356 (14-15), 3083-3091.
GHS危险和防护声明
危险说明(欧盟):H290-H302-H317-H318-H410
May be corrosive to metals. Harmful if swallowed. May cause an allergic skin reaction. Causes serious eye damage. Very toxic to aquatic life with long lasting effects.
防范说明:P261-P264b-P270-P272-P280-P302+P352-P305+P351+P338-P310-P330-P363-P390-P406b-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Wash contaminated clothing before reuse. Absorb spillage to prevent material damage. Store in corrosive resistant polypropylene container with a resistant inliner Dispose of contents/ container to an approved waste disposal plant
其他参考资料
文件
产品 SDS
质量分析报告(COA)
产品说明书