µ-Chloro-µ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene
化学性质
应用
µ-Chloro-µ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum is used in organic synthesis for carbonyl methylenation, A versatile methylenation reagent for the conversion of ketones and aldehydes to olefins, it offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers. Tebbe reagent can be used to olefinate aldehydes, to methylenate a chiral polyhydroxyketone with high diasteroselctivity.
注释
参考文献
GHS危险和防护声明
危险说明（欧盟）:H225-H304-H314-H336-H361-H373-H412
Highly flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes severe skin burns and eye damage. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects.
防范说明:P201-P202-P242-P260-P264b-P271-P281-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378r-P403+P233-P501c
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/ container to an approved waste disposal plant
其他参考资料
文件
产品 SDS
质量分析报告(COA)
