(R)-(+)-2,2"-Bis(di-p-tolylphosphino)-1,1"-binaphthyl, 98%
化学性质
应用
(R)-(+)-2,2"-Bis(di-p-tolylphosphino)-1,1"-binaphthyl is used as chiral catalyst ligand. (R)-T-BINAP complexes derived from rhodium precursors are used for the asymmetric hydroformylation of vinyl acetate. It is a catalysts used for reductive amination of ketones, Pt dications for cation trapping,Rh(I)-catalyst for hydrogenation of acetamidoacrylic acid derivatives.
注释
参考文献
Shun-Yi Wang; Shun-Jun Ji; Teck-Peng Loh. Cu(I) Tol-BINAP-catalyzed enantioselective Michael reactions of Grignard reagents and unsaturated esters.. Journal of the American Chemical Society. 2007, 129 (2), 276-277.
Charles A Mullen; Michel R Gagné. Catalytic asymmetric prins cyclizations: cation generation and trapping with (BINAP)Pt dications.. Organic Letters. 2006, 8 (4), 665-668.
GHS危险和防护声明
危险说明（欧盟）:H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
防范说明:P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Take off contaminated clothing and wash before reuse. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/ container to an approved waste disposal plant
其他参考资料
文件
产品 SDS
质量分析报告(COA)
