1,2,3,4,5-Pentamethylcyclopentadiene, 94%
化学性质
应用
1,2,3,4,5-Pentamethylcyclopentadiene serves as a precursor to the ligand 1,2,3,4,5-pentamethylcyclopentadienyl. It is used as a growth modifier chemical, during metal organic chemical vapor deposition of iron from iron pentacarbonyl. It is used as a ligand in "one-pot" iridium-catalyzed transformation of alcohols to amides. Further, it acts as an electron mediator in the regeneration process of nicotinamide adenine dinucleotide. In addition to this, it undergoes radical cation catalyzed cycloaddition reaction with allenes to get Diels-Alder product.
注释
参考文献
Liu, J.; Cazelles, R.; Chen, Z. P.; Zhou, H.; Galarneau, A.; Antonietti, M. The bioinspired construction of an ordered carbon nitride array for photocatalytic mediated enzymatic reduction. Phys. Chem. Chem. Phys. 2014, 16, 14699-14705.
Wulfers, M. J.; Jentoft, F. C. The Role of Cyclopentadienium Ions in Methanol-to-Hydrocarbons Chemistry. ACS Catal. 2014, 4 (10), 3521-3532.
GHS危险和防护声明
危险说明(欧盟):H226
Flammable liquid and vapour.
防范说明:P233-P241-P242-P280-P370+P378r-P403+P235-P501c
Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Store in a well-ventilated place. Keep cool. Dispose of contents/ container to an approved waste disposal plant
其他参考资料
文件
产品 SDS
质量分析报告(COA)
产品说明书