1,4-Cyclohexadiene, 97% stab. with 0.1% BHT
化学性质
应用
1,4-Cyclohexadiene is used to study the formation of parent ion from heavy fragmentation on irradiation with a high-intensity laser pulse. It is also used as a very effective hydrogen donor for catalytic hydrogenation reaction. It forms benzene at elevated temperatures in the presence of a ruthenium(II)-triphenylphosphine catalyst.
注释
参考文献
Mao, J. X.; Mathers, R. T. Damodaran, K. NMR spectroscopic and computational investigations of RuHCl(CO)(PPh3)3 catalyzed isomerization of 1,4-cyclohexadiene. J. Organomet. Chem. 2013, 741-742, 15-19.
Levandowski, B. J.; Houk, K. N. Theoretical Analysis of Reactivity Patterns in Diels-Alder Reactions of Cyclopentadiene, Cyclohexadiene, and Cycloheptadiene with Symmetrical and Unsymmetrical Dienophiles. J. Org. Chem. 2015, 80 (7), 3530-3537.
Kakinuma, S.; Shirota, H. Dynamic Kerr Effect Study on Six-Membered-Ring Molecular Liquids: Benzene, 1,3-Cyclohexadiene, 1,4-Cyclohexadiene, Cyclohexene, and Cyclohexane. J. Phys. Chem. B. 2015, 119 (13), 4713-4724.
GHS危险和防护声明
危险说明（欧盟）:H225
Highly flammable liquid and vapour.
防范说明:P233-P241-P242-P280-P370+P378r-P403+P235-P501c
Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Store in a well-ventilated place. Keep cool. Dispose of contents/ container to an approved waste disposal plant
其他参考资料
文件
产品 SDS
质量分析报告(COA)
产品说明书
