1,1"-Bis(dichlorophosphino)ferrocene, 98%
化学性质
应用
It is applied as a reactant for synthesis of ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation, metallocene-bridged bisphosphaalkene and as a catalyst for synthesis of oligonuclear heterometallic complexes.
注释
参考文献
Carmen Moser, et. al. The homologous series of 1,1"-ferrocenylenebisdihalophosphanes (C5H4PX2)2Fe (X = F, Cl, Br, I): precursors for the first metallocene bridged bisphosphaalkene.Dalton Trans.,2006,732(7), 3879-3885.
Xingao Peng, et al. Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation.Tetrahedron Lett.,2008,49(33), 4862-4864.
GHS危险和防护声明
危险说明(欧盟):H314
Causes severe skin burns and eye damage.
防范说明:P264b-P271-P280-P301+P330+P331-P304+P340-P305+P351+P338-P310-P363-P403+P233-P501c
Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/ container to an approved waste disposal plant
其他参考资料
文件
产品 SDS
质量分析报告(COA)
产品说明书