2-Methoxybenzylmagnesium chloride, 0.25M in 2-MeTHF
化学性质
应用
2-Methoxybenzylmagnesium chloride is a Grignard reagent used in organic synthesis. It is involved in the synthesis of (-)-Chamobtusin A. It is also used in the preparation of molybdenum and tungsten Alkylidene complexes having a tert-butylimido ligand.
注释
参考文献
Jeong, H.; Schrock, R. R.; Mu?ller, P. Synthesis of Molybdenum and Tungsten Alkylidene Complexes that Contain a tert-Butylimido Ligand. Organometallics 2015, 34 (17), 4408-4418.
Mena, M.; Valls, N.; Borregán, M.; Bonjoch, J. Synthesis of enantiopure cis-decahydroquinolines from homotyramines by Birch reduction and aminocyclization. Tetrahedron 2006, 62 (39), 9166-9173.
GHS危险和防护声明
危险说明(欧盟):H225-H302-H313-H315-H318
Highly flammable liquid and vapour. Harmful if swallowed. May be harmful in contact with skin. Causes skin irritation. Causes serious eye damage.
防范说明:P233-P242-P264b-P270-P280-P305+P351+P338-P310-P330-P363-P370+P378r-P403+P235-P501c
Keep container tightly closed. Use only non-sparking tools. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Wash contaminated clothing before reuse. In case of fire: Store in a well-ventilated place. Keep cool. Dispose of contents/ container to an approved waste disposal plant
其他参考资料
文件
产品 SDS
质量分析报告(COA)