3-Fluorophenylmagnesium bromide, 1M in MeTHF
化学性质
应用
3-Fluorophenylmagnesium bromide is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).
注释
参考文献
Sophie Marquais; Michael Arlt. Aryl-aryl cross coupling on a solid support using zinc organic reagents and palladium catalysis. Tetrahedron Letters. 1996, 37, (31),5491-5494
Ni Yan; Xiaozhong Liu; Joseph M.Fox. Facially selective and regioselective carbometalation of cyclopropenes by Aryl Grignard Reagents. J. Org. Chem. 2008, 73, (2),563-568
GHS危险和防护声明
危险说明(欧盟):H225-H261-H302-H314
Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. Causes severe skin burns and eye damage.
防范说明:P242-P264b-P270-P271-P280-P304+P340-P305+P351+P338-P310-P330-P331-P335+P334-P363-P370+P378r-P402+P404-P501c
Use only non-sparking tools. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Wash contaminated clothing before reuse. In case of fire: Store in a dry place. Store in a closed container. Dispose of contents/ container to an approved waste disposal plant
其他参考资料
文件
产品 SDS
质量分析报告(COA)
产品说明书