Tri-n-butyltin methoxide, 97%
化学性质
参考文献
Catalyst for transesterification under neutral conditions: Bull. Soc. Chim. Fr., 262 (1969).
/nReacts with alcohols, by exchange, to give tri-n-butylstannyl ethers. Those derived from 3-halo alcohols cyclize on heating to give substituted oxetanes: J. Organomet. Chem., 47, 337 (1973):
/n
Similarly, 4-halo alcohols give tetrahydrofurans: J. Organomet. Chem., 50, 121 (1973).
/nEnol acetates are converted to tin enolates which can undergo Pd-catalyzed coupling with aryl bromides to give arylacetones: Chem. Lett., 939 (1982); J. Chem. Soc., Chem. Commun., 344 (1983), and with vinyl bromides to give ß-unsaturated ketones: Bull. Chem. Soc. Jpn., 57, 242 (1984).
/nFor a review of organotin alkoxides in organic synthesis, see: Synthesis, 56, (1969).
/nGHS危险和防护声明
危险说明（欧盟）:H301-H312-H315-H319-H372-H410
Toxic if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Causes damage to organs through prolonged or repeated exposure. Very toxic to aquatic life with long lasting effects.
防范说明:P264b-P270-P280-P301+P310-P302+P352-P305+P351+P338-P312-P330-P362-P405-P501c
Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/ container to an approved waste disposal plant
其他参考资料
文件
产品 SDS
质量分析报告(COA)
产品说明书
