Bis(1,5-cyclooctadiene)nickel(0)
化学性质
应用
Bis(1,5-cyclooctadiene)nickel(0) is used as a catalyst for the cycloaddition of 1,3-dienes and is used to catalyze the addition of allyl phenyl sulfide to alkynes leading to 1,4-dienes. Also, it is involved as a catalyst for asymmetric alpha-arylation and heteroarylation of ketones with chloroarenes, stereoselective borylative ketone-diene coupling, cycloaddition of benzamides with internal alkynes and methyl carboxylation of homopropargylic alcohols.
注释
参考文献
Galletti, A. M. R.; Hayatifar, M. Highly active and easily accessible catalysts for vinyl polymerization of norbornene obtained by oxidative addition of salicylaldimine ligands to bis (1, 5-cyclooctadiene) nickel (0) and methylaluminoxane. J. Polym. Sci., Part A: Polym. Chem. 2012, 50 (21), 4459-4464.
Berlie, A.; Terry, I.; Szablewski, M. A Magnetic Study of Low Moment Nickel Clusters Formed from the Solid-State Decomposition Reaction of Nickel bis-1, 5-Cyclooctadiene. J. Cluster Sci. 2013, 24 (4), 1057-1066.
GHS危险和防护声明
危险说明（欧盟）:H228-H350
Flammable solid. May cause cancer.
防范说明:P201-P202-P261-P270-P272-P280-P302+P352-P308+P313-P363-P370+P378r-P403-P501c
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF exposed or concerned: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Store in a well-ventilated place. Dispose of contents/ container to an approved waste disposal plant
其他参考资料
文件
产品 SDS
质量分析报告(COA)
产品说明书
